Chemistry of Double-bonded Functional Groups (2 volume set) by Saul Patai

By Saul Patai

The 1st supplementary quantity in "The Chemistry of useful teams" sequence used to be released in 1976. This incorporated 13 chapters within the kind of essay-reviews complementing the unique major volumes within the sequence on C=C, C=O, C=N and N=N double bonds. As then, within the current moment complement A2, numerous of the authors have been requested to put in writing chapters which provide a unified and comparative therapy of a number of double-bonded useful teams jointly. This goal has been accomplished and certainly greater than half the chapters within the booklet are such integrative ones, focused within the first a part of the amount. different chapters care for certain matters which for varied purposes haven't been taken care of within the unique volumes or in complement A. The literature insurance in such a lot chapters is as much as in regards to the finish of 1987 and in certain cases even to the center of 1988.

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Extra resources for Chemistry of Double-bonded Functional Groups (2 volume set) (Chemistry of Functional Groups)

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There are several possibilities to circumvent the problem of isomerization. Field ionization (FI) seems to be an ideal solution, since the fragmentation is faster than the isomerization. Effectively, it has been shown by Levsen and coworkers64 for 19 olefins from C4 to C8 that the fragments thus obtained are typical for the location of the double bond. However, the difficulty to obtain reproducible results with the FI technique prevented widespread use. All methods that induce either a fragmentation that is faster than a shift of the double bond or use ionization energies at the threshold of the ionization energy are potentially useful candidates.

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Ni and Harrison122 studied the singly charged transition metal ions from ScC through CuC with six acyclic C5 H8 isomers. ScC , TiC and VC , produced by FAB ionization of the solid metal chlorides, give distinctly different spectra for all isomers investigated. CI spectra with MeNH2 as reagent gas have been studied by Budzikiewicz, Laufenberg and Brauner123 . , i-C4 H10 or NO) to straight-chain Z-alkenes. Addition to the double bond occurs also with E-di-, tri- and tetra-substituted and cyclic olefins.

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