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E. 52 moles. 6 kJ mol-1 for methane and 0 kJ mol-1 for oxygen and nitrogen (10). Since the initial temperature of the reactants is 298 K, the integral in Equation (14) is zero for methane, oxygen, and nitrogen. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2014. Equation (12) can now be written as follows: This equation is a nonlinear equation and a numerical method needs to be used in order to solve for the unknown Tad. A FORTRAN 77 routine is used to determine the zero of the nonlinear equation given above (14).
Reactions can also involve very large changes in pressure, heat, and volume, creating additional hazards that are not always anticipated, especially when changing the scale of the reaction. Recognition of these hazards is demonstrated by the extent of governmental regulations that must be followed when operating a chemical enterprise. Safety in Academia The sub-culture established in Academia reflects the segmented nature of the instruction schedule, the length of time designated for all lab tasks and instruction, the amount of academic credit given, and the other additional outside tasks that also compete for student time and attention.
Even the materials of the reaction vessel need to be considered. For example: a bench scale reaction may be conducted in a glass vessel. Will the reaction be impacted by conducting the reaction in a steel vessel? Changes in metallurgy or vessel requirements may impact the economics of the scale-up and the ultimate economic feasibility of the overall project. There are mechanical issues as well to be addressed. If the process requires mixing, or agitation; how is that to be accomplished at the larger scale?